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Upstream product

• 1179-06-2 1,4-Bis(diphenylphosphino)benzene 
• 540-36-3 para-difluorobenzene 
• 4559-70-0 Diphenylphosphine oxide 
• 106-37-6 1.4-dibromobenzene 
• 624-38-4 para-diiodobenzene 
• 1079-66-9 chloro-diphenylphosphine 
• 106-46-7 para-dichlorobenzene 
• 1499-21-4 Diphenylphosphinic chloride 

Relevant academic research and scientific papers

Ligand-Assisted Back Energy Transfer in Luminescent TbIII Complexes for Thermosensing Properties

A luminescent TbIII complex with a hexafluoroacetylacetone (hfa) ligand shows a characteristic back energy transfer (BEnT), which leads to high temperature sensitivity and potential application as a thermosensitive paint. Ligand-assisted BEnT was observed when a phosphine oxide ligand was introduced into Tb(hfa)3 complex, which was shown to affect the activation energy (ΔEa) and frequency factor (A) in the BEnT process between TbIII ion and hfa ligands. According to temperature-dependent emission-lifetime measurements of mononuclear Tb(hfa)3 complexes with monodentate phosphine oxides and polynuclear Tb(hfa)3 complexes with bidentate phosphine oxides, the ΔEa and A values of polynuclear TbIII complexes were smaller than those of mononuclear TbIII complexes. Phosphorescence spectra and lifetimes of each Gd(hfa)3 complex revealed that excited states of hfa ligands in TbIIIcomplexes differed from those of the polynuclear TbIII complexes and mononuclear TbIII complexes. The differences in the ΔEa and A values between polynuclear and mononuclear TbIII complexes were caused by the formation of different excited states, such as delocalization of the excited state in the polynuclear TbIII complexes and localization of excited states in the mononuclear TbIII complexes. In particular, small ΔEa and A values of polynuclear TbIII complexes provided high, effective activation of the BEnT at low temperature, which resulted in high-sensitive temperature-dependent phosphor materials over a wide temperature range.

1,4-phenylenebis(diphenylphosphine oxide)

The structure of the title compound, 1,4-C6H4[PO-(C6H5)2] 2 (C30H24O2P2), is the first to be reported of a phenylenebis(phosphine oxide). The mol

Palladium anchored on a covalent organic framework as a heterogeneous catalyst for phosphorylation of aryl bromides

A simple azine-linked covalent organic framework (COF) with high thermal and chemical stabilities has been prepared by using deep eutectic solvent (DES) as green media. The as-synthesized COF was employed as heterogeneous ligand for immobilization of PdII. The obtained Pd-supported COF nanoparticles catalyst (defined as Pd/TFPT-Azine-COF) was found to be an efficient heterogeneous catalyst for the Hirao reaction of aryl halides and dialkyl phosphites or diphenylphosphine oxide with excellent recyclability, reusability, and retention of crystallinity.

Compound containing bis-diphenyl phosphinic oxygen structure and preparation method thereof

The invention discloses a compound containing a bis-diphenyl phosphinic oxygen structure and a preparation method of the compound, and belongs to the technical field of organic synthesis. In a polar solvent, diphenyl phosphorus chloride or diphenyl phosph

Regulating structural dimensionality and emission colors by organic conjugation between SmIII at a fixed distance

The conjugation of bridging bis(diphenylphosphine oxide) alkane or arene ligands was found to control the structural dimensionality and the emission color of complexes from reactions with SmIII(hfac)3(H2O)2 (hfa

Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands

Three large-bite diphosphine dioxide ligands were reacted with lanthanide salts to yield either molecular or polymeric complexes. The two flexible ligands gave bischelate complexes of general formulae [Ln(dppfO2) 2Clx(NOs

Ni(II)/Zn catalyzed reductive coupling of aryl halides with diphenylphosphine oxide in water

P-Arylation in water has been developed via cross-coupling of aryl halides with diphenylphosphine oxide (Ph2P(O)H) and (RP)-(-)- menthyl benzylphosphinate catalyzed by NiCl2?6H2O/Zn under relatively mild conditions.

LIGHT-EMITTING DEVICE CONTAINING BIS-PHOSPHINEOXIDE COMPOUND

An OLED device comprises an anode and a cathode and having therebetween a light emitting layer containing an emissive material, wherein a layer between the anode and cathode contains a phosphineoxide compound bearing two or more tri(hetero)arylphosphineoxide groups, provided these groups are selected to give a compound with a Et ≥ 2.65 eV.