314254-50-7Relevant academic research and scientific papers
Syntheses and X-ray structures of (2,2′-biphosphinine)-(η5-pentamethylcyclopentadienyl)- ruthenium(I) dimer and ruthenium(0) complexes
Rosa,Ricard,Mathey,Le Floch
, p. 5247 - 5250 (2000)
Reduction of the [Ru(Cp*)(tmbp)Cl] complex (tmbp = 4,4′,5,5′-tetramethyl-2,2′-biphosphinine) with 1 and 2 equiv of sodium naphthalenide respectively yield a dimeric [Ru(Cp*)(tmbp)]2 complex and a [Ru(Cp*)(tmbp)][Na(DME)2] complex which were both structurally characterized. Trapping the Ru(0) complex with MeI, Ph3SnCl, Me3SnCl, or H+ affords the corresponding Ru(II) derivatives.
