314270-73-0

Basic information

• Product Name: 9-benzyloxy-3a-[2-benzyloxy-4-(tert-butyl-diphenyl-silanyloxy)-2-methyl-butyl]-8-(4,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yl)-5,10-dihydroxy-2,2-dimethyl-11,11a-dihydro-3aH-1,3-dioxa-cyclopenta[b]anthracen-4-one
• CAS NO: 314270-73-0
• Molecular Weight: 1147.49
• Mol File: 314270-73-0.mol

Chemical Properties

• CAS DataBase Reference: 9-benzyloxy-3a-[2-benzyloxy-4-(tert-butyl-diphenyl-silanyloxy)-2-methyl-butyl]-8-(4,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yl)-5,10-dihydroxy-2,2-dimethyl-11,11a-dihydro-3aH-1,3-dioxa-cyclopenta[b]anthracen-4-one(CAS DataBase Reference)
• NIST Chemistry Reference: 9-benzyloxy-3a-[2-benzyloxy-4-(tert-butyl-diphenyl-silanyloxy)-2-methyl-butyl]-8-(4,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yl)-5,10-dihydroxy-2,2-dimethyl-11,11a-dihydro-3aH-1,3-dioxa-cyclopenta[b]anthracen-4-one(314270-73-0)
• EPA Substance Registry System: 9-benzyloxy-3a-[2-benzyloxy-4-(tert-butyl-diphenyl-silanyloxy)-2-methyl-butyl]-8-(4,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yl)-5,10-dihydroxy-2,2-dimethyl-11,11a-dihydro-3aH-1,3-dioxa-cyclopenta[b]anthracen-4-one(314270-73-0)

Safety Data

• Hazardous Substances Data: 314270-73-0(Hazardous Substances Data)

Upstream product

• 314242-17-6 3a-[2-benzyloxy-4-(tert-butyl-diphenyl-silanyloxy)-2-methyl-butyl]-2,2-dimethyl-7,7a-dihydro-3aH-benzo[1,3]dioxol-4-one 

Downstream Products

• 314270-82-1 (3aR,11aR)-9-Benzyloxy-3a-((S)-2-benzyloxy-4-hydroxy-2-methyl-butyl)-8-((2R,4R,5R,6R)-4,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yl)-5,10-dimethoxy-2,2-dimethyl-11,11a-dihydro-3aH-1,3-dioxa-cyclopenta[b]anthracen-4-one 
• 314270-75-2 (R)-3-Benzyloxy-4-[(3aR,11aR)-9-benzyloxy-8-((2R,4R,5R,6R)-4,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yl)-5,10-dimethoxy-2,2-dimethyl-4-oxo-11,11a-dihydro-4H-1,3-dioxa-cyclopenta[b]anthracen-3a-yl]-3-methyl-butyraldehyde 
• 314270-74-1 9-benzyloxy-3a-[2-benzyloxy-4-(tert-butyl-diphenyl-silanyloxy)-2-methyl-butyl]-8-(4,5-bis-benzyloxy-6-methyl-tetrahydro-pyran-2-yl)-5,10-dimethoxy-2,2-dimethyl-11,11a-dihydro-3aH-1,3-dioxa-cyclopenta[b]anthracen-4-one 

Relevant articles and documents

Synthetic study of aquayamycin. Part 3: First total synthesis

The first total synthesis of aquayamycin (1) has been accomplished. The crucial steps include (1) the Hauser reaction between 3-(phenylsulfonyl)phthalide 3 and cyclohexenone 4 to make up the linear BCD tricycle, and (2) the intramolecular pinacol coupling