314733-86-3

Upstream product

• 204203-14-5 N-(2,6-diisopropylphenyl)-N-((1E)-1-(6-[(1E)-N-(2,6-diisopropylphenyl)ethanimidoyl]pyridin-2-yl)ethylidene)amine 
• 12081-16-2 dichlorotetraethylene dirhodium (I), 

Downstream Products

• 314733-89-6 (C₆H₃(C₃H₇)2NCCH₃)2C₅H₃NRhC₂H₄⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=(C₆H₃(C₃H₇)2NCCH₃)2C₅H₃NRhC₂H₄B(C₆H₃(CF₃)2)4 
• 756876-44-5 [Rh(CH₂Si(CH₃)3)(C₅H₃N(C(CH₃)N(C₆H₃(CH(CH₃)2)2))2)] 
• 756876-45-6 (C₅H₂N(C(CH₃)NC₆H₃(CH(CH₃)2)2)2)Rh(C₂H₄) 
• 756876-42-3 2,6-[2,6-(iPr)2C₆H₃NCMe]2C₅H₃NRhMe 
• 756876-43-4 [Rh(CH₂C₆H₅)(C₅H₃N(C(CH₃)N(C₆H₃(CH(CH₃)2)2))2)] 
• 1258601-47-6 [Rh(C₅H₃N(C(CH₃)NC₆H₃(C₃H₇)2)2)(N₂)] 
• 340820-72-6 [(C₅NH₃)(C(CH₃)N((C₆H₃)(i-C₃H₇)2))2Rh][B((C₆H₃)(CF₃)2)4] 
• 314733-87-4 (C₆H₃(C₃H₇)2NCCH₃)2C₅H₃NRh(CH₃)(OSO₂CF₃)2 

Relevant academic research and scientific papers

A d10 Ag(i) amine-borane σ-complex and comparison with a d8 Rh(i) analogue: Structures on the η1 to η2:η2 continuum

H3B·NMe3 σ-complexes of d8 [(L1)Rh][BArF4] and d10 [(L1)Ag][BArF4] (where L1 = 2,6-bis-[1-(2,6-diisopropylphenylimino)ethyl]pyridine) have been prepared and structurally characterised. Analysis of the molecular and electronic structures reveal important but subtle differences in the nature of the bonding in these σ-complexes, which differ only by the identity of the metal centre and the d-electron count. With Rh the amine-borane binds in an η2:η2 fashion, whereas at Ag the unsymmetrical {Ag?H3B·NMe3} unit suggests a structure lying between the η2:η2 and η1 extremes.

Transition metal complexes with sterically demanding ligands, 3. Synthetic access to square-planar terdentate pyridine-diimine rhodium(I) and iridium(I) methyl complexes: Successful detour via reactive triflate and methoxide complexes

The synthesis of novel square-planar, terdentate, aryl-substituted pyridine-diimine Rh(I) and Ir(I) chloro complexes from the free ligands and the bis(μ-chloro) ethylene-bridged dimers [(C2H4)RhIrCl]2 is reported. Since at

Stable, cationic alkyl-olefin complexes of ruthenium(II) and rhodium(III): effects of ligand geometry upon olefin insertion/alkyl migration

The syntheses of ruthenium(II) and rhodium(III) model complexes of the putative active species in the iron(II)/MMAO polymerization system are reported. The cationic ruthenium methyl ethylene complex 3 is a stable, isolable compound, which does not produce polyethylene under a variety of conditions. Likewise, the analogous rhodium complex 12 shows no appreciable polymerization activity, despite its similarity to existing rhodium complexes which are active catalysts for olefin polymerization. X-ray crystal structures of the cationic ruthenium bis(ethylene) complex 7 and the five-coordinate rhodium bis(triflate) methyl complex 9 are also presented.