314754-57-9

Basic information

• Product Name: 9H-Xanthene, 4,5-bis(chloromethyl)-2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-
• CAS NO: 314754-57-9
• Molecular Formula: C25H32Cl2O
• Molecular Weight: 419.434
• Mol File: 314754-57-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 9H-Xanthene, 4,5-bis(chloromethyl)-2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 9H-Xanthene, 4,5-bis(chloromethyl)-2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-(314754-57-9)
• EPA Substance Registry System: 9H-Xanthene, 4,5-bis(chloromethyl)-2,7-bis(1,1-dimethylethyl)-9,9-dimethyl-(314754-57-9)

Safety Data

• Hazardous Substances Data: 314754-57-9(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 130525-41-6 2,7-bis(1,1-dimethylethyl)-9,9-dimethylxanthene 
• 186903-60-6 (2,7-di-tert-butyl-5-hydroxymethyl-9,9-dimethyl-9H-xanthen-4-yl)-methanol 

Downstream Products

• 1431471-15-6 C₆₅H₇₂N₆O₃ 
• 1431471-14-5 C₆₇H₆₀N₆O₃ 
• 1444494-73-8 2,7-di-tert-butyl-4,5-bis(iodomethyl)-9,9-dimethyl-9H-xanthene 
• 314754-66-0 2,7-di-tert-butyl-9,9-dimethyl-5-(methyl 2,3,4-tri-O-benzyl-α-D-glucopyranosyd-6-yloxy)methyl-4-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosylthio)methylxanthene 
• 314754-14-8 2,7-di-tert-butyl-9,9-dimethyl-4-(2,3,4,6-tetra-O-benzyl-β-D-glucopranosylthio)methyl-5-(methyl 2,3,6-tri-O-benzyl-α-D-glucopyranosid-4-yloxy)methylxanthene 
• 314754-63-7 2,7-di-tert-butyl-4-chloromethyl-9,9-dimethyl-5-(methyl 2,3,6-tri-O-benzyl-α-D-glucopyranosid-4-yloxy)methylxanthene 
• 314754-62-6 2,7-di-tert-butyl-4-chloromethyl-9,9-dimethyl-5-(methyl 2,3,4-tri-O-benzyl-α-D-glucopyranosid-6-yloxy)methylxanthene 

Relevant articles and documents

Excimer emission and energy transfer in cofacial boradiazaindacene (BODIPY) dimers built on a xanthene scaffold

Using a rigid xanthene scaffold, a series of boradiazaindacene derivatives were synthesized. In some of these compounds, two boradiazaindacene derivatives were placed cofacially, resulting in significant inter-chromophoric interactions, including excimer

Investigations on leaving group based intra- versus intermolecular glycoside bond formation

Ligation of the glyscosyl donor to the glycossyl acceptor through th eleaving group was performed with the aim of enforcing glycoside bond formation by an intramolecular (1.x)-shift. To this end, systheses of alkoxypropenly (27a and b), and 7-alkoxy-4-oxaheptadienly thioglucopyranoside derivatives (35a, b and d) were carried out. Thier activation with thiophilic systems gave the expected glucopyranosides 5a, b and d in up to high chemical yields, yet modest anomeric control. Competition experiments showed that an intermolecular reaction course is favored in these reactions, although model considerations imply that convenient intramolecular (1,3)-, (1,4)- (1,5)-, and (1,9)-shifts, respectively, of the glycosyl donor to the acceptor are possible.