31500-44-4Relevant academic research and scientific papers
PREPARATION OF SOLVATED AND/OR UNSOLVATED SIMPLE AND MIXED DIARYLMAGNESIUMS
Screttas, Constantinos G.,Micha-Screttas, Maria
, p. 325 - 334 (1985)
Arylation of arylmagnesium halide etherates by aryllithium provides a convenient method of preparing ar2Mg(Et2O)2 or Ar2Mg(THF)2.The ether complexes can be completely desolvated but the THF complexes cannot.Mixed diarylmagnesium tetrahydrofuranates, Ar1Ar2Mg(THF)2, although coordinationally saturated, have 1H and 13C NMR spectra which suggest that they are fluxional.
