315241-83-9Relevant academic research and scientific papers
Catena-poly[[cyclo-tetra-μ-chlorotetracopper(I)]-bis{μ-3-[(2- morpholino-4-oxo-4,5-dihydro-1,3-thiazol-5-ylidene)methylphenoxy]propene} -2κN,1′η2;1η2,2′κN]
Goreshnik, Evgeny,Karpyak, Volodymyr,Mys'kiv, Marian
, p. m390-m392 (2005)
Crystals of a new copper(I) π complex of composition [Cu 4Cl4(C17H18N2O 3S)2]n have been obtained by alternating-current electrochemical synthesis. In the crystal structure, the Cu and Cl atoms form a chair-like Cu4Cl4 cyclic fragment. The organic ligand acts as a bridge, being connected via the C=C bond of the allyl group to a Cu atom from one inorganic cycle and via the N atom of the thiazole ring to a Cu atom of another copper-chloride fragment. The geometry of the π center indicates that the Cu-(C=C) interaction is moderately effective.
