31538-21-3Relevant articles and documents
Vanadium phosphorus oxide modified by silver doping: A highly effective catalyst for allylic oxidation of cycloolefins
Liu, Junhua,Wang, Fang,Ma, Zhenmao,Lin, Jun,Gu, Zhenggui
experimental part, p. 103 - 107 (2012/03/09)
Allylic oxidation of cycloolefins was carried out over Ag-VPO catalyst using tert-butyl hydroperoxide (TBHP) as oxidant in argon atmosphere, under our reaction conditions, attack of the activated C-H bonds was preferred instead of the epoxidation of C=C bond and corresponding α, β-enones were obtained as the main products. It is a high yielding, safe and eco-friendly method.