31554-20-8Relevant articles and documents
Nickel(0)-catalyzed [2 + 2 + 1] carbonylative cycloaddition of imines and alkynes or norbornene leading to γ-lactams
Hoshimoto, Yoichi,Ohata, Tomoya,Sasaoka, Yukari,Ohashi, Masato,Ogoshi, Sensuke
, p. 15877 - 15880 (2014)
The first nickel(0)-catalyzed [2 + 2 + 1] carbonylative cycloaddition reaction of imines and alkynes or norbornene has been achieved by employing phenyl formate as a CO source. With this method, a variety of N-benzenesulfonyl, -tosyl, and -phosphoryl-substituted γ-lactams can be prepared in good to high yields.