315664-57-4Relevant academic research and scientific papers
Tuning the Structure and Hydrolysis Stability of Calcium Metal-Organic Frameworks through Integrating Carboxylic/Phosphinic/Phosphonic Groups in Building Blocks
Sun, Jing,Huang, Tao,Yin, Qi,Li, Lan,Liu, Tian-Fu,Huang, Xin-Song,Cao, Rong
, p. 8021 - 8027 (2020)
Crystal structure and hydrolysis stability are fundamentally important for the application of metal-organic frameworks (MOFs) in biotechnology. Herein, five novel 3-D MOFs, built up from biocompatible calcium ions and ligands containing carboxylic, phosphinic, or phosphonic coordinating groups, have been solvothermally synthesized, and their crystal structures were determined by single-crystal X-ray diffraction. Their hydrolysis stability study demonstrated that the water stability of these Ca-based MOFs can be tuned by integrating carboxylic/phosphinic/phosphonic coordinating groups in building blocks.
