31582-87-3

Basic information

• Product Name: 1-chloro-4-(cyclohexyloxy)benzene
• Synonyms: 1-chloro-4-(cyclohexyloxy)benzene
• CAS NO: 31582-87-3
• Molecular Weight: 210.704
• Mol File: 31582-87-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-chloro-4-(cyclohexyloxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-chloro-4-(cyclohexyloxy)benzene(31582-87-3)
• EPA Substance Registry System: 1-chloro-4-(cyclohexyloxy)benzene(31582-87-3)

Safety Data

• Hazardous Substances Data: 31582-87-3(Hazardous Substances Data)

Upstream product

• 110-82-7 cyclohexane 
• 2206-38-4 cyclohexylphenyl ether 

Relevant articles and documents

Kaolin-assisted Aromatic Chlorination and Bromination

Moist kaolin catalyses the regioselective and high-yielding chlorination and bromination of C6H5OR (R = C1-C8 alkyl. Bu1, allyl, cyclohexyl, benzyl) to 4-XC6H4OR (X = Cl and Br, respectively) with NaCl02 and Mn(acac)3 in CH2Cl2 in the absence and presence of NaBr, respectively, under mild and neutral conditions.

Regiospecific aromatic chlorination of alkyl phenyl ethers using sodium chlorite catalysed by manganese(III) acetylacetonate and moist alumina in dichloromethane

A solid-liquid biphasic system (dichloromethane and chromatographic neutral alumina) has been tested for the aromatic chlorination of various alkyl aryl ethers using a reagent combination of sodium chlorite and manganese(III) acetylacetonate catalyst. Efficient incorporation of a chlorine atom into the benzene ring with high para-selectivity results. This catalytic system is also applicable to the regiocontrolled chlorination of polyether substrates.