31604-30-5Relevant articles and documents
The regioselective generation of arynes from polyhalogenobenzenes. An improved synthesis of syn- and anti-1,4,5,8,9,12-hexahydro-1,4:5,8:9,12-triepoxytriphenylene
Raymo, Francisco,Kohnke, Franz H.,Cardullo, Francesca,Girreser, Ulrich,Fraser Stoddart
, p. 6827 - 6838 (1992)
The halogenated benzenes, 1,2,4,5-tetrabromobenzene 6, hexabromobenzene 9, p-dichlorotetrabromobenzene 11, and 1,2-dibromo-4,5-dichlorobenzene 12, were investigated as 1,3-bis-, 1,4-bis-, and 1,3,5-tris-aryne precursors by using alkyllithiums and alkali m
A novel graphite-like stacking structure in a discrete molecule and its molecular recognition behavior
Akine, Shigehisa,Onuma, Takahiro,Nabeshima, Tatsuya
supporting information, p. 9369 - 9372 (2018/06/18)
A graphite-like stacking structure was nicely reproduced in a discrete molecule that was prepared by 2+2 macrocyclic Schiff base formation. In the crystal structure, two hexabenzocoronene planes are closely stacked with displacement, yielding the intramolecular stacking structure similar to an AB- or ABC-stacking pattern in natural graphite. This molecule showed a recognition ability toward electron-deficient aromatic molecules in solution.
PERBROMINATION OF BENZENE AND SOME OF ITS DERIVATIVES
Golounin, A. V.,Shukhta, T. K.,Kirienko, E. K.,Petrova, M. P.,Esavkin, E. V.
, p. 1167 - 1169 (2007/10/02)
Perbrominated compounds - pentabromophenol, hexabromobenzene, pentabromotoluene, polychlorobromobenzenes, and decabromodiphenyl ether - have been obtained.Substitution bromination has been discovered in treating diphenyl sulfoxide, diphenyl sulfide, diphenylmethane, diphenyl oxide, and benzophenone with excess bromine in the presence of AlBr3.A series of ethers and esters of pentabromophenol have been obtained; their hydrolysis has been carried out.A negative influence of ferric halides has been discovered in exhaustive bromination of aromatic compounds.