316372-83-5

Upstream product

• 6111-99-5 ethyl diazoalaninate 
• 629-05-0 n-octyne 

Downstream Products

• 1094064-57-9 ((CH₃C₆H₄)3P)AuC₄O₂(C₆H₁₃)(H)(CH₃) 
• 1094064-60-4 ((p-MeC₆H₄)3P)Au(C₄HO(O)(CH₃)(n-C₆H₁₃)) 
• 1094064-61-5 ((p-MeOC₆H₄)3P)Au(C₄HO(O)(CH₃)(n-C₆H₁₃)) 
• 1094064-58-0 ((CH₃C₆H₄)3P)AuC₄O₂(C₆H₁₃)(H)(CH₃) 
• 1094064-62-6 ((C₆H₁₁)3P)AuC₄O₂(C₆H₁₃)(H)(CH₃) 
• 1052691-13-0 C₂₀H₂₆O₃ 
• 1052691-10-7 C₂₃H₃₄O₃ 

Relevant academic research and scientific papers

Copper-catalyzed synthesis of 2,4-disubstituted allenoates from α-diazoesters

Chemical equations presented. A Cu-catalyzed method for coupling α-substituted-α-diazoesters with terminal alkynes to give substituted allenoates is described. Key to the development of a selective method was the recognition that an adventitous base catalyzes the isomerization to form the allenoate product. A plausible mechanism is proposed, based in part on evidence against a mechanism that involves a Cu(I)-acetylide as a low-valent intermediate.