316382-36-2

Upstream product

• 13242-53-0 acetobromomannose 
• 316382-33-9 allyl 4-O-acetyl-2,3-O-isopropylidene-6-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-β-D-mannopyranoside 
• 316382-32-8 allyl 2,3-O-isopropylidene-6-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-β-D-mannopyranoside 
• 316382-31-7 allyl 6-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-β-D-mannopyranoside 
• 85249-43-0 allyl-β-D-mannopyranoside 
• 119111-32-9 allyl 2,3,4,6-tetra-O-acetyl-β-D-mannopyranoside 
• 3947-62-4 2,3,4,6-tetra-O-acetyl-D-mannopyranose 
• 83-87-4 D-Mannose pentaacetate 
• 60046-31-3 2,3,5-tri-O-benzoyl-L-arabinofuranosyl bromide 
• 316382-34-0 allyl 4-O-acetyl-6-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-β-D-mannopyranoside 

Downstream Products

• 316382-37-3 allyl 2-O-(2,3,5-tri-O-benzoyl-α-L-arabinofuranosyl)-3,4-di-O-acetyl-6-O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-β-D-mannopyranoside 

Relevant academic research and scientific papers

Synthesis of allyl 2-O-(α-L-arabinofuranosyl)-6-O-(α-D-mannopyranosyl)-β-D-mannop yranoside, a unique plant N-glycan motif containing arabinose

The synthesis of the trisaccharide allyl 2-O-(α-L-arabinofuranosyl)-6-O-(α-D-mannopyranosyl)-β-D-mannop yranoside is reported. Stereoselective glycosylation at C-6 of a non-protected allyl β-mannoside with the acetylated α-D-mannosyl bromide gave the α-(1 → 6)-disaccharide as the main product and the crystalline 3,6-branched trisaccharide as minor compound. Further glycosylation of the 2,3 diol (1 → 6) disaccharide with L-arabinofuranosyl bromide furnished a mixture of 3-O- and 2-O-α-L-Ara-trisaccharides from which the title compound was isolated. (C) 2000 Elsevier Science Ltd.