31650-28-9

Upstream product

• 188290-36-0 thiophene 
• 149-74-6 dichloromethylphenylsilane 
• 3141-27-3 2,5-dibromothiophen 
• 2786-07-4 2-thienyl lithium 
• 1003-09-4 2-bromothiophene 
• 96-43-5 2-thienyl chloride 

Downstream Products

• 3959-13-5 methyl(phenyl)silanediol 

Relevant academic research and scientific papers

Bis(2-thienyl)silanes: new, versatile precursors to arylsilanediols

Silanediols have been shown to be effective bioisosteres for the hydrated carbonyl group. Current methods for the formation of silanediols place a number of constraints on how and where this functionality may be used. A range of arylsilanes that would allow both the formation of arylsilanediols and that are also compatible with multi-step synthetic routes, have been investigated as possible precursors to silanediols. Through this study bis(2-furyl)silanes and, in particular, bis(2-thienyl)silanes have been identified as practical precursors to arylsilanediols.

Electrochemical synthesis of bis(2-thienyl) silanes, 2-thienylchlorosilanes, bis[5-(2-bromothienyl)]silanes, and 5-(2-bromothienyl) dimethylchlorosilane, precursors of poly[(silanylene) thiophene]s

Bis(2-thienyl)silanes and bis[5-(2-bromothienyl)]silanes were synthesized by electrochemical reduction of monohalothiophenes (Br,C1) and 2,5-dibromothiophene respectively in the presence of a dichlorosilane in THF or DME, using an undivided cell, a sacrif

Syntheses and Electrical Properties of Organosilicon Polymers Containing Thiophene and Anthraquinone Units

Organosilicon polymers containing thiophene and anthraquinone units in the main chain were synthesized using palladium catalyst.These polymers were soluble and showed a small UV absorption change by the substituents on the silicon atom.Some of the polymers exhibit cation doping (n-doping) by the electrochemical reduction, and this doping process seemed to depend on the kinds of substituents on silicon atom.These polymers showed electrical conductivity of 3 * 10-5 S cm1- when doped with sodium naphthalenide.