3166-26-5Relevant academic research and scientific papers
Synthesis of α-arylthioacetones using TEMPO as the: C 3 synthon via a reaction cascade of sequential oxidation, skeletal rearrangement and C-S bond formation
Zou, Jiao-Xia,Jiang, Yi,Lei, Shuai,Yin, Gao-Feng,Hu, Xiao-Ling,Zhao, Quan-Yi,Wang, Zhen
supporting information, p. 2341 - 2345 (2019/03/07)
Here, we present an unprecedented pathway to α-sulfenylated carbonyl compounds from commercially available thiols and universally employed TEMPO and its analogues, which act as C3 synthons through skeletal rearrangement under simple and metal-f
Kinetic resolution of heteroaryl β-hydroxy sulfides catalyzed by Humicola lanuginosa lipase
Chimni, Swapandeep Singh,Singh, Satwinder,Kumar, Subodh,Mahajan, Savita
, p. 511 - 517 (2007/10/03)
Humicola lanuginosa lipase-catalyzed resolution of heteroaryl substituted β-hydroxy sulfides by irreversible transesterification using vinyl acetate as acylating agent is discussed. The ee of the resolved alcohols was determined from the 1H NMR of their corresponding (S)-(+)-O-acetylmandelic acid esters.
