316813-66-8

Basic information

• Product Name: Allyl-((Z)-(S)-1-phenyl-but-2-enyl)-carbamic acid tert-butyl ester
• Synonyms: Allyl-((Z)-(S)-1-phenyl-but-2-enyl)-carbamic acid tert-butyl ester
• CAS NO: 316813-66-8
• Molecular Weight: 287.402
• Mol File: 316813-66-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Allyl-((Z)-(S)-1-phenyl-but-2-enyl)-carbamic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Allyl-((Z)-(S)-1-phenyl-but-2-enyl)-carbamic acid tert-butyl ester(316813-66-8)
• EPA Substance Registry System: Allyl-((Z)-(S)-1-phenyl-but-2-enyl)-carbamic acid tert-butyl ester(316813-66-8)

Safety Data

• Hazardous Substances Data: 316813-66-8(Hazardous Substances Data)

Upstream product

• 316813-29-3 (E)-(R)-2-Benzenesulfonyl-1-phenyl-but-2-enylamine 
• 316813-12-4 (1R,2S)-2-Benzenesulfonyl-1-phenyl-but-3-enylamine 
• 350479-90-2 (S,E)-N-benzylidene-4-methylbenzenesulfinamide 
• 13139-12-3 tert-butyl 2,5-dioxopyrrolidin-1-yl carbonate 
• 316813-41-9 Allyl-((Z)-(S)-1-phenyl-but-2-enyl)-amine 
• 316813-33-9 Allyl-((E)-(R)-2-benzenesulfonyl-1-phenyl-but-2-enyl)-amine 

Downstream Products

• 1006-64-0 (S)-2-phenylpyrrolidine 
• 174310-75-9 2-phenylpyrrolidine-1-carboxylic acid tert-butyl ester 
• 316813-68-0 (2S)-N-tert-butoxycarbonyl-2-phenyl-2,5-dihydropyrrole 

Relevant articles and documents

Synthesis of enantiopure pyrrolidine and piperidine derivatives via ring closing metathesis

The additions of lithiated allylsulfone carbanion to chiral N-sulfinylimines were found to proceed with good to excellent selectivity. The resulting intermediates 4a-d after transformation to dienylamides 7a-d and 16a-d, were converted to functionalized enantiopure piperidines and pyrrolines, respectively, via ring closing metathesis (RCM). (C) 2000 Elsevier Science Ltd.