317845-74-2Relevant academic research and scientific papers
Synthesis of δ-lactones from 2-alkynyl epoxides and 4-alkynyl-1,3-dioxolan-2-ones by palladium catalysed carbonylation and conjugate nucleophilic addition
Knight, Julian G.,Ainge, Simon W.,Baxter, Carl A.,Eastman, Timothy P.,Harwood, Simon J.
, p. 3188 - 3190 (2000)
Synthesis of δ-lactones from 2-alkynyl epoxides and 4-alkynyl-1,3-dioxolan-2-ones by palladium catalysed carbonylation and conjugate nucleophilic addition was investigated. The stereocontrolled conjugate addition of nucleophiles to the electron deficient
Copper-catalyzed silylation reactions of propargyl epoxides: Easy access to 2,3-allenols and stereodefined alkenes
Chang, Xi-Hao,Liu, Zheng-Li,Luo, Yun-Cheng,Yang, Chao,Liu, Xiao-Wei,Da, Bing-Chao,Li, Jie-Jun,Ahmad, Tanveer,Loh, Teck-Peng,Xu, Yun-He
, p. 9344 - 9347 (2017/08/23)
Efficient silylation reactions of propargyl epoxides catalyzed by copper catalysts have been developed. Under mild reaction conditions, tri- and tetra-substituted functionalized allenols and alkenes could be selectively obtained in moderate to high yields
