31836-20-1

Basic information

• Product Name: 2-nitrophenyl chlorothioformate
• Synonyms: 2-nitrophenyl chlorothioformate
• CAS NO: 31836-20-1
• Molecular Weight: 217.633
• Mol File: 31836-20-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-nitrophenyl chlorothioformate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-nitrophenyl chlorothioformate(31836-20-1)
• EPA Substance Registry System: 2-nitrophenyl chlorothioformate(31836-20-1)

Safety Data

• Hazardous Substances Data: 31836-20-1(Hazardous Substances Data)

Upstream product

• 463-71-8 thiophosgene 
• 88-75-5 2-hydroxynitrobenzene 

Downstream Products

• 92335-56-3 thiocarbonic acid O-methyl ester-O'-(2-nitro-phenyl ester) 
• 94215-33-5 thiocarbonic acid O-(2-nitro-phenyl ester)-O'-propyl ester 
• 97497-86-4 thiocarbonic acid O-(2-nitro-phenyl ester)-O'-octyl ester 
• 93193-00-1 thiocarbonic acid O-ethyl ester-O'-(2-nitro-phenyl ester) 
• 96651-30-8 thiocarbonic acid O-(2-nitro-phenyl ester)-O'-pentyl ester 
• 95348-56-4 thiocarbonic acid O-heptyl ester-O'-(2-nitro-phenyl ester) 
• 26392-43-8 thiocarbonic acid O-benzyl ester-O'-(2-nitro-phenyl ester) 
• 94982-46-4 thiocarbonic acid O-butyl ester-O'-(2-nitro-phenyl ester) 
• 96874-38-3 thiocarbonic acid O-hexyl ester-O'-(2-nitro-phenyl ester) 
• 1047648-43-0 1-(chlorodifluoromethoxy)-2-nitrobenzene 
• 2719-30-4 o-nitrophenylisothiocyanate 

Relevant articles and documents

Preparation of alkyl and aryl chlorodifluoromethyl ethers using BrF 3

Both alkyl and aryl chlorothioformates could readily be obtained from the corresponding alcohols and thiophosgene. These families of compounds were treated with BrF3 to form the corresponding alkyl and aryl chlorodifluoromethyl ethers in 60-85% yields. The method is suitable for constructing a variety of aliphatic as well as electron-deficient aromatic chlorodifluoromethyl ethers. The reactions proceed under mild conditions and short reaction times. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.