31843-92-2Relevant academic research and scientific papers
Reaction of enol ethers with the I2-H2O2 system: Synthesis of 2-iodo-1-methoxy hydroperoxides and their deperoxidation and demethoxylation to 2-iodo ketones
Terent'ev, Alexander O.,Borisov, Alexander M.,Platonov, Maxim M.,Starikova, Zoya A.,Chernyshev, Vladimir V.,Nikishin, Gennady I.
experimental part, p. 4159 - 4166 (2011/03/18)
The reaction of enol ethers with the I2-H2O 2 system in diethyl ether affords 2-iodo ketones and the previously unknown 2-iodo-1-methoxy hydroperoxides. In the presence of the I 2-H2O2 system, the latter compounds undergo deperoxidation and demethoxylation to form 2-iodo ketones. The reaction conditions were found for the synthesis of 2-iodo ketones from enol ethers in 67-94% yields. Georg Thieme Verlag Stuttgart - New York.
