31865-49-3

Basic information

• Product Name: 1-Cyclohexyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane
• Synonyms: 1-Cyclohexyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane
• CAS NO: 31865-49-3
• Molecular Formula: C₁₂H₂₃NO₃Si
• Molecular Weight: 257.4014
• Mol File: 31865-49-3.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 329°Cat760mmHg
• Flash Point: 152.8°C
• Appearance: /
• Density: 1.1g/cm³
• Vapor Pressure: 0.000182mmHg at 25°C
• Refractive Index: 1.509
• CAS DataBase Reference: 1-Cyclohexyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclohexyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane(31865-49-3)
• EPA Substance Registry System: 1-Cyclohexyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane(31865-49-3)

Safety Data

• Hazardous Substances Data: 31865-49-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H23NO3Si/c1-2-4-12(5-3-1)17-14-9-6-13(7-10-15-17)8-11-16-17/h12H,1-11H2

Upstream product

• 102-71-6 triethanolamine 
• 18151-84-3 cyclohexyltriethoxysilane 

Downstream Products

• 24371-94-6 cyclohexylmercury chloride 

Relevant articles and documents

DIRECT TRANSFER OF ALIPHATIC AND AROMATIC SUBSTITUENTS FROM ORGANOSILATRANES TO MERCURY(II) SPECIES

The relative reaction rates of several silatranes (derivatives of 2,8,9-trioxa-5-aza-1-silatricyclo1,5>undecane) and HgCl2 in acetone-d6 to yield the corresponding organomercury compound are of the order of e.g., 5 * 10-1 1 mol-1 sec-1 or slightly less, a rate that is unexpectedly high compared to the essentially inert parent organotrialkoxysilanes.Thus, the apical Si-C bond of the silatrane is extraordinarily susceptible to direct electrophilic attack by mercury(II).The rates decrease in the order CH2=CH, C6H5, p-ClC6H4 > CH3 > CH3CH2, CH3CH2CH2 > C6H11, ClCH2, Cl2CH, CH3CH2O.The effects of varying the solvent and the counterions are noted, and the probable mechanism is discussed.