3188-75-8Relevant academic research and scientific papers
Fluorine-containing cationic polymerization monomer as well as synthesis and application thereof
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Paragraph 0139-0141; 0201; 0203, (2020/05/05)
The present invention relates to a monomeric compound of formula (I), wherein the variables are as defined in the specification. The monomer is rapidly synthesized with a high yield through a click chemical reaction between mercaptan and olefin. Moreover, a basically perfluorinated alkane chain is introduced into the oxa-cycloalkane monomer by virtue of a connecting group containing a norbornane structure part, so that the photo-cured film obtained by photo-curing the obtained monomer cation is high in surface hardness, low in surface energy, excellent in hydrophobic and oleophobic properties,and particularly very good in oil stain resistance. The invention also relates to a preparation method of the monomer, a polymer obtained by ring-opening polymerization of the monomer, a photo-curable composition containing the monomer and a photo-curable material obtained by photo-curing of the photo-curable composition.
Norbornene compounds with cross-linkable groups and their derivatives
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Page/Page column 24, (2010/11/24)
The present invention provided a norbornene compound with cross-linkable groups and their derivative polymers, wherein said cross-linkable groups were olefin or epoxy groups. Norbornene polymers with cross-linkable side chain and their block copolymers as well as modified derivatives were prepared via living ring-open metathesis polymerization method. The resulting polymers with excellent solubility and optic properties had narrow molecular weight distribution, well-controlled molecular weight, small refraction ration and high transparency. They were also suitable for preparing hybrid materials with high thermal stability and chemical resistance.
