31895-21-3 Usage
Uses
Thiocyclam is a pro-insecticide of the natural
toxin nereistoxin and is rapidly converted into the
latter in biological media. It has limited systemic activity
with stomach and contact action. It causes paralysis
by ganglionic blocking action on the insect central nervous
system. It is used as the hydrogen oxalate salt. This is converted
to the active nereistoxin, and its oxide in soils and
plants and these are ultimately broken down into smaller
molecules.
Definition
ChEBI: An organosulfur heterocyclic compound that is 1,2,3-trithiane in which one of the hydrogens at position 5 has been replaced by a dimethylamino group. A nicotinic acetylcholine receptor agonist, it was used (particularly as its hydrogen oxalate salt, known
s thyocyclam oxalate) as a broad-spectrum insecticide, but it is also toxic to bees, fish and other aquatic organisms. It is not approved for use within the European Union.
Check Digit Verification of cas no
The CAS Registry Mumber 31895-21-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,1,8,9 and 5 respectively; the second part has 2 digits, 2 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 31895-21:
(7*3)+(6*1)+(5*8)+(4*9)+(3*5)+(2*2)+(1*1)=123
123 % 10 = 3
So 31895-21-3 is a valid CAS Registry Number.
InChI:InChI=1/C5H11NS3/c1-6(2)5-3-7-9-8-4-5/h5H,3-4H2,1-2H3
31895-21-3Relevant articles and documents
A New Group of Compounds Derived from Nereistoxin - Synthesis of Bis-dimethylamino-tris-disulfanes
Muehlstaedt, M.,Heinicke, J.,Schubert H.
, p. 841 - 847 (2007/10/02)
The reaction of organo-thiosulfates, BUNTE-salts, with mercaptans is a convenient synthesis of disulfanes.Similarly bis-BUNTE-salt 7 and tert. butyl mercaptan give bis-disulfane 5c.By treating 7 with several aliphatic mercaptans we found the formation of the tris-disulfanes 8a-d in preparative amounts in addition to the bis-disulfanes 5a-d expected.This reaction was investigated.The preparation of the compounds 8 is described and a proposal is given for a mechanism of the formation of 8 as a thiol-disulfide-interchange.
