31989-52-3

Upstream product

• 96165-44-5 {1,2-bis(dicyclohexylphosphino)ethane}dichloropalladium(II) 
• 906373-73-7 [(1,2-bis(dicyclohexylphosphino)ethane)Pd(H)SiH(t-Bu)2] 
• 148572-28-5 {(μ2-1,2-bis(dicyclohexylphosphino)ethane)palladium(0)}2 
• 23743-26-2 1,2-bis-(dicyclohexylphosphino)ethane 
• 149478-10-4 {Pd(C₂H₄)(1,3-bis(diphenylphosphino)propane)} 
• 6737-42-4 1,3-bis-(diphenylphosphino)propane 

Downstream Products

• 144435-67-6 [(1,2-bis(dicyclohexylphosphinoethane)Pd(SiHMe₂)2] 
• 906373-73-7 [(1,2-bis(dicyclohexylphosphino)ethane)Pd(H)SiH(t-Bu)2] 

Relevant academic research and scientific papers

Palladium-Catalysed C?H Bond Zincation of Arenes: Scope, Mechanism, and the Role of Heterometallic Intermediates

Catalytic methods that transform C?H bonds into C?X bonds are of paramount importance in synthesis. A particular focus has been the generation of organoboranes, organosilanes and organostannanes from simple hydrocarbons (X=B, Si, Sn). Despite the importan

Dynamic processes in silyl palladium complexes: Evidence for intermediate Si-H and Si-Si σ-complexes

The silyl palladium complexes (dcpe)PdH(SiHtBu2) and (dcpe)Pd(SiHMe2)2 display NMR spectra that vary with temperature. The dynamic NMR behavior is consistent with long-lived σ-complexes as intermediates. In the case of (dcpe)PdH(SiHtBu2), the intermediate is believed to be a symmetric complex with doubly bridged hydrogen atoms between the silicon and palladium. Dynamic interchange of the two silicon atoms in (dcpe)Pd(SiHMe2)2 is consistent with an intermediate Si-Si σ-complex. Copyright