319906-88-2

Basic information

• Product Name: (-)-(1R,4R,5S)-4-Benzyloxymethylbicyclo[3.2.1]octan-2-one
• Synonyms: (-)-(1R,4R,5S)-4-Benzyloxymethylbicyclo[3.2.1]octan-2-one
• CAS NO: 319906-88-2
• Molecular Weight: 244.334
• Mol File: 319906-88-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (-)-(1R,4R,5S)-4-Benzyloxymethylbicyclo[3.2.1]octan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(1R,4R,5S)-4-Benzyloxymethylbicyclo[3.2.1]octan-2-one(319906-88-2)
• EPA Substance Registry System: (-)-(1R,4R,5S)-4-Benzyloxymethylbicyclo[3.2.1]octan-2-one(319906-88-2)

Safety Data

• Hazardous Substances Data: 319906-88-2(Hazardous Substances Data)

Upstream product

• 319906-86-0 (+)-(1R,2S,5R)-2-Benzyloxymethylbicyclo[3.2.1]oct-3-en-2-ol 
• 66222-28-4 (benzyloxymethyl)tributylstannane 
• 497-38-1 2-norbornanone 
• 237736-41-3 (-)-endo-Bicyclo[3.2.1]oct-3-en-2-ol 
• 319906-87-1 (-)-(1R,5S)-4-Benzyloxymethylbicyclo[3.2.1]oct-3-en-2-one 
• 79027-21-7 (+)-Bicyclo<3.2.1>oct-3-en-2-one 
• 57722-40-4 2-trimethylsilyloxybicyclo<2.2.1>hept-2-ene 
• 99957-00-3 Trimethyl-((1S,2S,4S,5R)-tricyclo[3.2.1.0^2,4]oct-2-yloxy)-silane 
• 3212-77-9 bicyclo<3.2.1>oct-3-en-2-one 
• 39762-77-1 endo-bicyclo<3.2.1.>oct-3-en-2-yl acetate 
• 32222-49-4 endo-bicyclo<3.2.1>oct-3-en-2-ol 

Downstream Products

• 319906-89-3 (+)-(1R,5R,6S)-5-Benzyloxymethyloxabicyclo[4.2.1]nonan-3-one 
• 319906-93-9 (+)-(3S)-3-[(1R)-2-Benzyloxy-1-vinylethyl]cyclopentan-1-one 
• 319906-91-7 (-)-(3S)-3-[(1R)-1-Benzyloxymethyl-3-hydroxypropyl]cyclopentan-1-one 
• 319906-90-6 (-)-(1R,3S)-3-[(1R)-1-Benzyloxymethyl-3-hydroxypropyl]cyclopentan-1-ol 
• 319906-94-0 (+)-(4R)-4-[(1R)-2-Benzyloxy-1-vinylethyl]-2,2-propanedithiocyclopentan-1-one 

Relevant articles and documents

Diastereodivergent synthesis of the C9-cyclopentanone chiral building blocks

Diastereodivergent synthesis the C9-cyclopentanone chiral building block, serving as the non-tryptamine moiety of the Corynanthe type indole alkaloids and the related natural products, and its diastereomer has been developed from racemic norcamphor by employing lipase-mediated resolution via an allylic acetate intermediate having a bicyclo[3.2.1]octane framework. A potential of the latter diastereomer has been demonstrated by its conversion into (-)-semburin, a monoterpene isolated from Swertia japonica previously and obtained from the C9-block.