319923-28-9Relevant academic research and scientific papers
Acid-catalyzed synthesis of α,β-disubstituted conjugated enones by a Meyer-Schuster-type rearrangement in allenols
Alcaide, Benito,Almendros, Pedro,Cembellín, Sara,Martínez Del Campo, Teresa
supporting information, p. 1070 - 1078 (2015/03/30)
A novel, direct and simple methodology to gain access to α,β-disubstituted conjugated enones from α-allenols in a sustainable metal catalysis context, considering the inexpensiveness and environmentally friendliness of iron(III) species and protons, has b
Direct allenol-based stereocontrolled access to substituted (E)-1,3-enynes
Alcaide, Benito,Almendros, Pedro,Martínez Del Campo, Teresa
, p. 7603 - 7609 (2012/10/29)
A stereoselective synthesis of 1-substituted (E)-2-aryl-but-1-en-3-ynes, including tetrasubstituted alkenes, has been developed from aryl-substituted α-allenols by treatment with the AcCl-NaOH (aqueous) system. This transformation might be explained throu
