31996-83-5Relevant academic research and scientific papers
β-CARBONYL RADICALS AS THREE-CARBON BUILDING BLOCKS FOR CARBON-CARBON BOND FORMING REACTIONS
Giese, Bernd,Horler, Hans
, p. 4025 - 4038 (2007/10/02)
From aldehydes, ketones and esters β-carbonyl radicals 47 can be generated via enolization, cyclopropanation, solvomercuration and reduction with NaBH4.Radicals 47 react with electron-poor alkenes 27 to give products of CC-bond forming reactions (Tables 1-3).Carbonyl compounds are therefore precursors of three-carbon building blocks.The products result from reactions with "Umpolung".
