320343-98-4Relevant academic research and scientific papers
Zirconium complexes of a tacn-derived amido ligand and ring-opening to form a new diamido-amino pincer
Giesbrecht,Shafir,Arnold
, p. 2135 - 2136 (2000)
The tribenzyl complex (Pr(i)2tacn)Zr(CH2Ph)3 eliminates toluene upon heating with concomitant ring-opening of the anionic ancillary macrocycle to yield [CH2=CHNCH2- CH2N(Pr(i))CH2CH2NPr(i)]Zr(CH2Ph)2; the latter features a new class of dianionic pincer ligand.
