32042-78-7

Upstream product

• 62244-76-2 Acetic acid (S)-8a-methyl-1,2,3,4,6,7,8,8a-octahydro-naphthalen-1-yl ester 
• 13304-34-2 (S)-8a-Methyl-1,2,3,4,6,7,8,8a-octahydro-naphthalen-1-ol 
• 108-24-7 acetic anhydride 
• 257935-93-6 4,4a,5,6,7,8-hexahydro-5-hydroxy-4-methylnaphthalen-2(3H)-one 

Downstream Products

• 87262-05-3 4β-Hydroxy-4aβ-methyl-3,4,4a,5,6,8aα-hexahydronaphthalene-1(2H),7(8H)-dione 7-dimethyl acetal 
• 53078-17-4 1β-acetoxy-8aβ-methyl-1,2,3,4,6,7,8,8a-octahydronaphthalen-6-one 
• 878-47-7 (4aS,5S)-4,4a,5,6,7,8-hexahydro-5-hydroxy-4a-methylnaphthalen-2(3H)-one 
• 34996-06-0 (4αR,5R)-5-hydroxy-4α-methyl-4,4α,5,6,7,8-hexahydronaphthalen-2(3H)-one 
• 770-62-7 trans-8a-Methyl-octahydro-1(2H)-naphthalinon 
• 84102-23-8 (1aα,2E,4aβ,5β)-<4a-Methyl-5-(4-methylphenylsulfonyloxy)-4,4a,5,6,7,8-hexahydro-1aH-naphth<1,8a-b>oxiren-2-(3H)-yliden>essigsaeure-methylester 
• 84102-23-8 (1aα,2Z,4aβ,5β)-<4a-Methyl-5-(4-methylphenylsulfonyloxy)-4,4a,5,6,7,8-hexahydro-1aH-naphth<1,8a-b>oxiren-2-(3H)-yliden>essigsaeure-methylester 
• 84102-19-2 (1aα,4aβ,5β)-(4a-Methyl-2-oxo-2,3,4,4a,5,6,7,8-octahydro-1aH-naphth<1,8a-b>oxiren-5-yl)-p-toluolsulfonat 
• 84102-29-4 (5aα,6α,9aα,9bα)-9a-Hydroxy-5a-methyl-6-(4-methylphenylsulfonyloxy)-5,5a,6,7,8,9,9a,9b-octahydronaphtho<1,2-b>furan-2(4H)-on 
• 84102-40-9 (3aα,5aα,6α,9aα,9bα)-9a-Hydroxy-5a-methyl-6-(4-methylphenylsulfonyloxy)-3a,4,5,5a,6,7,8,9,9a,9b-decahydronaphtho<1,2-b>furan-2(3H)-on 
• 87262-45-1 (1S,4aR,8aS)-6-[1-Methoxy-1-phenylsulfanyl-meth-(Z)-ylidene]-8a-methyl-4-methylene-decahydro-naphthalen-1-ol 
• 97400-51-6 4-(5'-hydroxy-2'-methylphenyl)butanal 
• 136379-64-1 (4α,4aα,8aβ)-4-[(tert-Butyldimethylsilyl)oxy]octahydro-7,7-dimethoxy-4a-methyl-1(2H)-naphthalenone 
• 97094-19-4 octahydro-4aα-hydroxy-4β,8aβ-dimethyl-6β-(1-methylethenyl)-1(2H)-naphthalenone 

Relevant academic research and scientific papers

A New Method for the Oxidation of Alkenes to Enones. An Efficient Synthesis of Δ5-7-Oxo-Steroids

A variety of cycloalkenes were converted into α,β-unsaturated ketones using t-butyl hydroperoxide in the presence of chromium hexacarbonyl catalyst.The scope of the reaction has been partly invstigated, and it was found that the allylic oxidation proceeds selectively in the presence of some secondary alcohols.High-yield conversions of steroidal 5,6-enes into the corresponding 5,6-en-7-ones are reported.