320779-57-5

Upstream product

• 96-32-2 bromoacetic acid methyl ester 
• 264186-55-2 (+)-(2S,3E)-2-[(tert-butyldiphenylsilyl)oxy]non-3-enenitrile 

Downstream Products

• 320779-61-1 (-)-(1S,3S,4S)-1-acetoxy-3-tert-butyldiphenylsilyloxy-4-((E)-hept-1-enyl)tetrahydrofuran 
• 319925-34-3 (-)-(4S,5S)-4-tert-butyldiphenylsilyloxy-5-((E)-hept-1-enyl)tetrahydrofuran-2-one 
• 320779-64-4 (-)-(4R,5S)-4-tert-butyldiphenylsilyloxy-5-((E)-hept-1-enyl)tetrahydrofuran-2-one 

Relevant academic research and scientific papers

A novel stereoselective access to substituted L-2-deoxypentono-1,4-lactones and L-2-deoxypentoses

A stereoselective method to L-2-deoxypentose or L-2-deoxy-pentono-1,4-lactone units was developed employing the (S)-Hydroxynitrile lyase from Hevea brasiliensis. Additionally a diastereoselective reduction using either (D)- or (L)-tartaric acid in conjuction with sodium borohydride had been applied to control the ultimate stereochemistry of the bioactive compounds. (C) 2000 Elsevier Science Ltd.