32082-46-5

Upstream product

• 14187-32-7 dibenzo-18-crown-6 

Downstream Products

• 133415-12-0 1,5-bis(2'-methoxy-5'-nitrophenoxy)-3-hydroxypentane 
• 61853-51-8 2,3,12,13-tetranitro-6,7,9,10,17,18,20,21-octahydro-5,8,11,16,19,22-hexaoxadibenzo[b,k]cyclooctadecene 
• 118060-28-9 20,21,24-trinitro-2,3,11,12-dibenzo-1,4,7,10,13,16-hexaoxacyclooctadeca-2,11-diene 
• 133415-11-9 1,5-bis(2'-hydroxy-5'-nitrophenoxy)-3-hydroxypentane 
• 293300-55-7 cis-di((4-nitrophenylcarboxamido)benzo)-18-crown-6 
• 133429-87-5 5-(2'-methoxy-5'-nitrophenoxy)-3-hydroxypentan-1-ol 

Relevant academic research and scientific papers

Synthesis of Isomeric Dinitro and Diamino Derivatives of Polycyclic Crown Ethers: Dibenzo-18-crown-6 and Dibenzo-24-crown-8

Specific features of the synthesis of polycyclic crown ethers dibenzo-18-crown-6 and dibenzo-24-crown-8 and their dinitro and diamino derivatives have been studied. A mixture of isomers of dibenzocrown ether derivatives was obtained and separated. The spectral and thermal characteristics of the synthesized compounds and the kinetics of synthesis of dibenzo-24-crown-8 by the two-component condensation of pyrocatechol with 1-chloro-2-[2-(2-chloroethoxy)ethoxy]ethane in an alcoholic medium in the presence of a KOH template agent were studied.

Tr?ger's base-linked poly(crown ethers)s

Described herein are double-strand chain compositions suitable for use in the preparation of proton conductive membranes. The double-strand chains comprise a plurality of constitutional units joined to each other through two atoms on one side of the constitutional unit and two atoms on the other side of the constitutional unit. Constitutional units comprise a dibenzo-crown ether macrocycle fused with a bicyclic aliphatic linker. Polymers, membranes, and fuel cells comprising the double-strand chain are also described herein.

Benzo- and dibenzo-crown ethers substituted with (azulene-1-yl) azo chromophores. Synthesis and properties

Colored benzo- and dibenzo-crown ethers with (azulene-1-yl) azo chromophores(s) at benzo ring(s) were synthesized in good yields starting from the amines of the benzo- and dibenzo-crown ethers which were diazotized and coupled with azulenes. The obtained crown ethers were characterized and several properties of the generated new dyes were investigated (electronic and NMR-spectra, as well as pKa values, the lipophilicity and the coordination with metal cations).

Nitration of benzo crown ethers with potassium nitrate in polyphosphoric acid

A general method for the nitration of benzo crown ethers with potassium nitrate in polyphosphoric acid has been developed. Mono- and dinitro derivatives of benzo-12-crown-4, benzo-15-crown-5, dibenzo-18-crown-6, and dibenzo-24-crown-8 have been prepared. The role of complex formation in the regioselective tendency for the nitration of dibenzo-18-crown-6 has been demonstrated.

A macrobicyclic receptor with versatile recognition properties: Simultaneous binding of an ion pair and selective complexation of dimethylsulfoxide

A bicyclic receptor was synthesized and evaluated for its ability to bind alkali halide salts and polar neutral molecules in organic solvents. The receptor design is relatively straightforward in the sense that it is a combination of a dibenzo-18-crown-6

Synthesis of Isomeric Dihydroxy Derivatives of Dibenzo-18-crown-6

In 1967 Pedersen described dibenzo-18-crown-6 (1).We report the preparation of its isomeric dihydroxy derivatives 2c and 3c.Nitration of 1 in acetic acid and chloroform yields the dinitro compounds 2a and 3a. 2a and 3a have different solubility in ethylene glycol monomethyl ether and can be separated.Catalytic reduction of the dinitro derivatives with hydrazine and Raney nickel leads to the diamines 2b and 3b.The diazonium salts of 2b and 3b are heated in dilute sulfuric acid and yield the phenols 2c and 3c. - Key words: Dibenzo-18-crown-6, Isomeric Dihydroxy Derivatives