32111-91-4Relevant academic research and scientific papers
N-(4-Chlorophenyl)-N-methylcyanamide
Cunningham, Ian D.,Light, Mark E.,Hursthouse, Michael B.
, p. 1833 - 1835 (1999)
An X-ray structural analysis of the title compound, C8H7ClN2, shows an essentially planar molecule, but with an unusually long aryl-C to planar-N bond.
Acidity and N-methylation of N-aryl-N′-cyanoguanidines
Cunningham, Ian D.,Cox, Brian G.,Wan, Nan Chi,Povey, David C.,Smith, Gallienus W.
, p. 693 - 697 (2007/10/03)
Acid dissociation constants in water have been determined for proton loss from a series of N-aryl-N′-cyanoguanidines 1. Treatment of the same compounds with a strong base, butyllithium, followed by excess methyl iodide leads to successive N-methylation to yield mono-, di- and tri-methylated N-aryl-N′-cyanoguanidines. The mechanism of the methylation is discussed.
ARYLAZOMETHYLENETRIPHENYLPHOSPHORANES: A STUDY OF THE ALKYLATION REACTION
Alemagna, Andreina,Buttero, Paolo Del,Licandro, Emanuela,Papagni, Antonio
, p. 249 - 252 (2007/10/02)
The title compounds undergo alkylation reaction at the nitrogen β to the ylidic carbon atom: the nature of the reaction products depends on the alkylating reagent and on the nature of the solvent.
