32114-49-1

Upstream product

• 64-17-5 ethanol 
• 117-78-2 anthraquinone-2-carboxylic acid 
• 74-96-4 ethyl bromide 
• 13235-08-0 anthraquinone-2-carboxylic acid sodium salt 
• 130-15-4 [1,4]naphthoquinone 
• 84-54-8 2-methylanthracene-9,10-dione 
• 6470-87-7 anthraquinone-2-carbonyl chloride 
• 6363-86-6 2-formyl-9,10-anthraquinone 

Downstream Products

• 121991-40-0 2-(4,5-diphenyl-4H-[1,2,4]triazol-3-yl)-anthraquinone 

Relevant academic research and scientific papers

Spectroscopic Studies on the Intramolecular Hydrogen Abstraction Reaction of n-Alkyl Anthraquinone-2-carboxylates

Chain lenghts dependence of the intramolecular hydrogen abstraction reaction of n-alkyl anthraquinone-2-carboxylates (AQ-n, n=2-20) has been studied by steady-state photolysis, phophorescence, laser flash photolysis, and two-step laser induced fluorescence spectroscopies.All the results indicate that the excited triplet of the anthraquinone chromophore abstracts a hydrogen atom from its methylene side chain, whose rate increases with increasing chain lenght.The rate constant of AQ-8 is 1E4 s-1 and the increase in the rate is about 1.5E4 s-1 per one additional methylene unit for n>/=10.

Diels–Alder reactions of an elusive 1,3-butadiene bearing 2-carboxy and 4-alkoxy substituents

A reactive diene, ethyl 2-methylene-4-(pent-3-oxy)but-2-enoate, bearing electron-withdrawing carboxy and electron-donating pentoxy substituents is prepared and trapped in situ by a variety of dienophiles to form [4+2] cycloaddition products. Diels–Alder reaction of this diene with fumarate esters gives multiply substituted cyclohexenes that are useful for building the scaffold of oseltamivir.