321165-56-4Relevant academic research and scientific papers
Reactivity of diynes with a 1-azavinylidene-bridged triruthenium carbonyl cluster. Insertion reactions of diynes into Ru-H, Ru-C, and Ru-N bonds
Cabeza, Javier A.,Grepioni, Fabrizia,Moreno, Marta,Riera, Víctor
, p. 5424 - 5430 (2008/10/08)
The reactivity of the 1-azavinylidene cluster complex [Ru3(μ-H)(μ-N=CPh2)(CO)10] (1) with diynes has been studied. The nonconjugated diyne 1-trimethylsilyl-1,4-pentadiyne affords the binuclear ynenyl derivative [Ru2(μ-N=CPh2)(μ-η2-CH 2=CCH2C=CSiMe3)(CO)6] (2), which results from cluster fragmentation and from the insertion of the terminal alkyne fragment of the diyne into a Ru-H bond.
