321378-09-0Relevant articles and documents
An efficient formal synthesis of (-)-balanol by using ruthenium-catalyzed asymmetric hydrogenation
Phansavath, Phannarath,De Paule, Sebastien Duprat,Ratovelomanana-Vidal, Virginie,Genet, Jean-Pierre
, p. 3903 - 3907 (2007/10/03)
An efficient formal synthesis of (-)-balanol is reported. The ten-step sequence leading to a key precursor 4 features a highly stereoselective synthesis of the functionalized hexahydroazepine core through dynamic kinetic resolution of a racemic α-amido β-