321921-75-9

Upstream product

• 321921-74-8 C₁₃H₁₆O₂ 
• 1125-88-8 benzaldehyde dimethyl acetal 

Downstream Products

• 1258861-78-7 (3S,4R,5R,6S,10S,12S)-3-benzyloxy-10-(tert-butyldimethylsilyloxy)-12-methoxymethoxy-4,6-dimethyl-5-trimethylsilyloxy-pentadec-1-en-8-yn-7-one 
• 1258861-79-8 (3S,4R,5R,6S,10S,12S)-3-benzyloxy-10-(tert-butyldimethylsilyloxy)-12-methoxymethoxy-4,6-dimethyl-5-hydroxy-pentadec-1-en-8-yn-7-one 
• 1258861-80-1 (3S,4R,5R,6S,7S,10S,12S)-3-benzyloxy-10-(tert-butyldimethylsilyloxy)-12-methoxymethoxy-4,6-dimethylpentadec-1-en-8-yn-5,7-diol 
• 1258861-67-4 (3S,5S)-1-[(4S,5S,6R)-6-((2R,3S)-2-methyl-3-benzyloxy-buta-3-enyl)-2-phenyl-5-methyl-1,3-dioxan-4-yl]-3-tert-butyldimethylsilyl-5-methoxymethoxy-1-octyne 
• 1258861-69-6 C₁₃H₁₆O₂ 
• 1258861-70-9 (2S,3R,4S,5S)-5-benzyloxy-1-[(4R)-4-benzyl-2-thioxo-oxazolidin-3-yl]-3-hydroxy-2,4-dimethyl-hept-6-en-1-one 
• 1258861-68-5 C₂₁H₃₅NO₄Si 
• 1258861-71-0 (2S,3R,4R,5S)-5-benzyloxy-1-[(4R)-4-benzyl-2-thioxo-oxazolidin-3-yl]-3-hydroxy-2,4-dimethyl-hept-6-en-1-one 
• 1258861-83-4 C₃₅H₆₂O₆Si₂ 
• 321921-80-6 1-[(2S,3R,4R)-3-Benzyloxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-pentyloxymethyl]-4-methoxy-benzene 
• 321921-69-1 (2R,3R,4S)-4-methyl-5-[(4-methoxyphenyl)methoxy]-3-(phenylmethoxy) pentan-1,2-diol 
• 321921-76-0 (3R,4S)-4-methyl-5-[(4-methoxyphenyl)methoxy]-3-(phenylmethoxy)-1-pentene 

Relevant academic research and scientific papers

Studies on synthesis of the C-1 to C-18 fragment of pamamycins 607 and 621A

Some efforts directed towards synthesis of the C-1 to C-18 fragment of natural antibiotic pamamycins 607 and 621A are disclosed. The nine stereogenic centers in the fragment were installed using a chiral auxiliary-induced asymmetric aldol reaction, a chir

Asymmetric epoxide cyclisation route to the F-pyran fragment of the altohyrtins and key aldol studies

The evolution of an asymmetric synthesis of a differentially protected F-pyran ring of the altohyrtins is described, which relies on a key intramolecular cyclisation of a C43 hydroxyl group onto a C38-C39 epoxide. The C38-C39 epoxide stereochemistry was achieved through optimisation of substrate control. Key aldol studies towards coupling the F-pyran ring with an E-pyran ring precursor was investigated, but unsuccessful. (C) 2000 Elsevier Science Ltd.