32229-19-9Relevant articles and documents
Bromination of Anisoles Using N-Bromophthalimide: A Synthetic and Kinetic Approach
Anjaiah,Kumar, M. Satish,Srinivas,Rajanna
, p. 98 - 105 (2016)
N-Bromophthalimide (NBP)-triggered bromination of aromatic compounds has been studied in the presence of aqueous acetic acid. Reaction Kinetics indicated first order in [NBP] and zero order in [Anisole]. The reactions afforded very good yields of corresponding bromo derivatives under kinetic conditions. The mechanism of the reaction is explained through the formation of acetyl hypobromite due to the interaction of NBP and acetic acid, which in turn reacts with anisole to afford a bromo derivative of anisole.
Tropos deoxycholic acid-derived biphenylphosphites: synthesis, stereochemical characterization and use as chiral ligands in the copper catalyzed conjugate addition of diethylzinc to acyclic enones
Facchetti, Sarah,Losi, Debora,Iuliano, Anna
, p. 2993 - 3003 (2007/10/03)
Three new deoxycholic acid-based 5,5′-substituted biphenylphosphites, 2-4, were synthesized and their stereochemical features were examined by CD and NMR spectroscopy, which allowed us to determine the sense of twist of the substituted biphenyl moiety as