3224-44-0

Basic information

• Product Name: hexyl naphthalene-2-carboxylate
• Synonyms: 2-naphthalenecarboxylic acid, hexyl ester; Hexyl 2-naphthoate
• CAS NO: 3224-44-0
• Molecular Formula: C₁₇H₂₀O₂
• Molecular Weight: 256.3395
• Mol File: 3224-44-0.mol

Chemical Properties

• Boiling Point: 375.8°C at 760 mmHg
• Flash Point: 159°C
• Density: 1.05g/cm³
• Vapor Pressure: 7.56E-06mmHg at 25°C
• Refractive Index: 1.561
• CAS DataBase Reference: hexyl naphthalene-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: hexyl naphthalene-2-carboxylate(3224-44-0)
• EPA Substance Registry System: hexyl naphthalene-2-carboxylate(3224-44-0)

Safety Data

• Hazardous Substances Data: 3224-44-0(Hazardous Substances Data)

Upstream product

• 2243-83-6 2-naphthaloyl chloride 
• 111-27-3 hexan-1-ol 
• 93-09-4 naphthalene-2-carboxylate 
• 66-99-9 β-naphthaldehyde 

Relevant articles and documents

Preparation method for synthesizing ester compound by using N-Boc amide as raw material

The invention relates to a preparation method for synthesizing an ester compound by using N-Boc amide as a raw material. According to the method, an inorganic base is used as a catalyst; the N-Boc amide is subjected to an intermolecular nucleophilic substitution reaction with various alcohol compounds; and various ester compounds can be efficiently obtained. The method has the advantages of beingmild in reaction condition, simple and convenient to operate, high in yield and favorable in functional-group compatibility.

Cesium Carbonate Catalyzed Esterification of N-Benzyl- N-Boc-amides under Ambient Conditions

We report a general activated amide to ester transformation catalyzed by Cs2CO3. Using this approach, esterification proceeds under relatively mild conditions and without the need for a transition metal catalyst. This method exhibits broad substrate scope and represents a practical alternative to existing esterification strategies. The synthetic utility of this protocol is demonstrated via the facile synthesis of crown ether derivatives and the late-stage modification of a representative natural product and several sugars in reasonable yields.

Generally applicable and efficient esterification of aldehydes with alcohols catalyzed by cyclopalladated ferrocenylimine

The palladacycle-catalyzed esterification of a variety of aldehydes with alcohols was developed. This reaction allows formation of esters in moderate to excellent yields not only for various aldehydes but also alcohols. In addition, the esterification could proceed well under mild conditions with a low catalyst loading of 0.0625 mol%. Copyright