3225-27-2Relevant articles and documents
Novel 2,2,6,6-tetramethylpiperidine 1-oxyl-iodobenzene hybrid catalyst for oxidation of primary alcohols to carboxylic acids
Yakura, Takayuki,Ozono, Ayaka
, p. 855 - 859 (2011)
Novel bifunctional hybrid-type catalysts bearing 2,2,6,6- tetramethylpiperidine-1-oxyl (TEMPO) and iodobenzene moieties (1a and 1b) were developed and used for the environmentally benign oxidation of primary alcohols to carboxylic acids. Reaction of primary alcohols 2 with a catalytic amount of 1 in the presence of peracetic acid as a co-oxidant under mild conditions gave the corresponding carboxylic acids 3 in excellent yields.
A time-resolved electron paramagnetic resonance investigation of the spin exchange and chemical interactions of reactive free radicals with isotopically symmetric (14N-X-14N) and isotopically asymmetric ( 14N-X-15
Sartori, Elena,Khudyakov, Igor V.,Lei, Xuegong,Turro, Nicholas J.
, p. 7785 - 7792 (2008/02/09)
Interactions between reactive free radicals (r) with stable mononitroxyl radicals (N) and bisnitroxyl radicals (N-X-N) were studied by time-resolved electron paramagnetic resonance (TR-EPR). Reactive spin-polarized free radicals (r#), with non-