32285-86-2Relevant academic research and scientific papers
Chemoselective reduction of a lactam carbonyl group in the presence of a gem-dicarboxylate by sodium borohydride and iodine: A facile entry to N-aryl trisubstituted pyrroles
Haldar, Pranab,Ray, Jayanta K.
, p. 8229 - 8231 (2007/10/03)
Several N-aryl γ-lactam gem dicarboxylates were chemoselectively reduced to cyclic amine diesters by using sodium borohydride-iodine system. The reduction in all cases was completed within 2.5 h after refluxing in THF. The cyclic amine products were isolated after aqueous (acidic) workup in good yields. Hydrolytic decarboxylation followed by dehydrogenation produced N-aryl carboethoxy pyrroles.
SYNTHESIS OF SOME 9-ARYL-9-AZA-2,8-DIOXO-4,5-BENZOBICYCLONONANE, A NEW HETEROCYCLIC SYSTEM
Ghosh, Malay,Kar, Gandhi K. Ray, Jayanta K.,Chatterjee, Basanta G.
, p. 667 - 676 (2007/10/02)
A new and vaersatile synthetic procedure for the title compound is reported.Two routes for the cyclization of diazoketones (4) has been developed.
