3233-05-4Relevant academic research and scientific papers
Enantioselective syntheses of β-amino alcohols catalyzed by recyclable chiral Fe(III) metal complex
Tak, Rajkumar,Kumar, Manish,Kureshy, Rukhsana I.,Choudhary, Manoj Kumar,Khan, Noor-Ul H.,Abdi, Sayed H. R.,Bajaj, Hari C.
, p. 7693 - 7700 (2016/07/13)
An efficient asymmetric desymmetrization of meso-epoxides with anilines catalysed by a series of simple and environmentally benign in situ generated Fe(iii) complexes based on chiral tridentate ligands L1-L7 with achiral and chiral l
Insight into O2-promoted base-catalyzed N-alkylation of amines with alcohols
Wang, Chao,Chen, Changpeng,Han, Jian,Zhang, Jingyu,Yao, Yingming,Zhao, Yingsheng
supporting information, p. 2972 - 2977 (2015/04/27)
A highly efficient and practical transition-metal-free CsOH/O2 catalyst system was developed for the N-alkylation of amines with alcohols under argon. This strategy was compatible with many alcohols and exhibits excellent functional group tolerance. More significantly, the selective formation of secondary amines was achieved in excellent yields. The detailed mechanistic study gave a clear understanding of the role of base and oxygen in the catalytic cycle.
Synthesis of β-amino alcohols catalyzed by poly(vinyl chloride)-supported Schiff base metal complexes
Krishnan, G. Rajesh,Kajal, K. Sapna,Sreekumar, Krishnapillai
experimental part, p. 637 - 642 (2012/08/13)
Eight transition metal complexes of various Schiff bases supported on poly(vinyl chloride) (PVC) were prepared and characterized. These metal complexes were screened as heterogeneous catalysts in the synthesis of β-amino alcohols by ring opening of epoxid
Efficient radical domino approach to β-aminoalcohols from arylamines and alcohols triggered by Ti(III)/t-BuOOH
Spaccini, Raffaele,Ghilardi, Alessandra,Pastori, Nadia,Clerici, Angelo,Punta, Carlo,Porta, Ombretta
supporting information; experimental part, p. 2044 - 2052 (2010/04/26)
We report that an aqueous Ti(III)/t-BuOOH system promotes the efficient domino radical reaction of arylamines with alcohol cosolvents leading to β-aminoalcohols in good yields, in less than ten minutes at room temperature. The free-radical mechanism accor
