32337-99-8Relevant academic research and scientific papers
Multiple Resonance Effect-Induced Sky-Blue Thermally Activated Delayed Fluorescence with a Narrow Emission Band
Oda, Susumu,Kawakami, Bungo,Kawasumi, Ryosuke,Okita, Ryota,Hatakeyama, Takuji
, p. 9311 - 9314 (2019)
Efficient thermally activated delayed fluorescence materials based on the multiple resonance effect were synthesized by nucleophilic substitution and electrophilic C-H borylation, featuring a small energy gap between the singlet and triplet state, high ph
Solvent-Vapor-Induced Reversible Single-Crystal-to-Single-Crystal Transformation of a Triphosphaazatriangulene-Based Metal–Organic Framework
Hatakeyama, Takuji,Horike, Satoshi,Kamakura, Yoshinobu,Nakatsuka, Soichiro,Tanaka, Daisuke,Watanabe, Yusuke
, p. 1435 - 1439 (2020)
A triphosphaazatriangulene (H3L) was synthesized through an intramolecular triple phospha-Friedel–Crafts reaction. The H3L triangulene contains three phosphinate groups and an extended π-conjugated framework, which enables the stimul
Intramolecular Borylation via Sequential B?Mes Bond Cleavage for the Divergent Synthesis of B,N,B-Doped Benzo[4]helicenes
Kn?ller, Julius A.,Meng, Guoyun,Wang, Xiang,Hall, David,Pershin, Anton,Beljonne, David,Olivier, Yoann,Laschat, Sabine,Zysman-Colman, Eli,Wang, Suning
supporting information, p. 3156 - 3160 (2020/01/25)
New symmetric and unsymmetric B,N,B-doped benzo[4]helicenes 3–6 a/b have been achieved in good yields, using a three-step process, starting from N(tolyl)3 in a highly divergent manner (7 examples). A borinic acid functionalized 1,4-B,N-anthrace
MECHANISM OF BROMINATION OF SOME AROMATIC AMIDES BY N-BROMOSUCCINIMIDE
Koshechko, V. G.,Inozemtsev, A. N.
, p. 315 - 318 (2007/10/02)
It was established that in polar organic solvents N-bromosuccinimide acts as a one-electron oxidizing agent for tertiary aromatic amines and N,N-substituted dihydrophenazines.Depending on the structure of the amines and the nature of the medium, the maximum current concentration of the radical-cations in these reactions amounts to 90percent of the initial amine.It was shown that the intermediate radical-cations of the substituted amines can then be transformed into the bromination products by reaction with the bromide ion formed during dissociation of the bromosuccinimide radical- anion.The mechanism of the investigated reactions in the light and in the dark is discussed.
