32341-36-9Relevant academic research and scientific papers
The synthesis and structural characterisation of some azo-containing phosphine chalcogenides and comparison to non-phosphorus-containing analogues
Alder,Bates,Cross,Flower,Pritchard
, p. 2669 - 2675 (2001)
p-HO-Ph(Ph2)P(E) (E=S, 1b, Se, 1c) reacts with the diazonium salts [4-R-PhN=N][BF4] (R=H, Me, Et, iPr, tBu, NMe2, NO2) to afford the new compounds [1-HO-2-(4-R-PhN=N)-4-Ph2P(E)C
Thiophosphoryl-, thiophosphoryloxy-, and thiophosphorylamino-benzene derivatives as novel classes of hybrid pincer ligands
Kozlov, Vladimir A.,Aleksanyan, Diana V.,Vasilev, Andrei A.,Odinets, Irina L.
scheme or table, p. 626 - 637 (2011/06/22)
The synthetic approaches to novel families of SCE (E = S',N,O) hybrid pincertype ligands bearing thophosphoryl, thiophosphoryloxy, and thiophosphorylamino groups in various combinations with thiophosphoryl-, thiocarbamoyl-, and imine- (including that of benzothiazole ring) donating functions have been developed. All of the ligands readily undergo direct cyclometallation (metal = Pd(II), Pt(II)) to afford 5,5- or 5,6-membered pincer complexes. Palladium complexes displayed from high to excellent catalytic performance in the Suzuki cross-coupling reaction of aryl bromides and phenylboronic acid and the higher asymmetry for a complex served as a factor of its higher catalytic activity. Copyright Taylor & Francis Group, LLC.
5,6-Membered palladium pincer complexes of 1-thiophosphoryloxy-3- thiophosphorylbenzenes. Synthesis, X-ray structure, and catalytic activity
Kozlov,Aleksanyan,Nelyubina, Yu. V.,Lyssenko,Gutsul,Vasil'Ev,Petrovskii,Odinets
, p. 8657 - 8666 (2011/01/08)
Novel unsymmetrical ligands, 1-thiophosphoryloxy-3-thiophosphorylbenzenes 3a-d, bearing phosphine sulfide and thiophosphoryloxy moieties as coordinating sites, were found to undergo cyclometalation at the C-2 position of the central benzene ring in a reac
