32375-29-4Relevant academic research and scientific papers
Charge Distribution Between Formally Identical Fragments: The McLafferty Rearrangement
Turecek, F.,Hanus, V.
, p. 8 - 12 (2007/10/02)
The McLafferty rearrangement for 2,5-diphenyl-1-hexene and its deuterium labelled analogues has been investigated.The α-methylstyrene fragments originating from different parts of the molecular ion retain the charge with equal probability and afford identical metastable spectra.The geometry of the transition state is discussed.
