32381-42-3

Basic information

• Product Name: 9-Undecenoic acid, 11-[(2R,3S)-3-pentyloxiranyl]-, (9Z)-
• CAS NO: 32381-42-3
• Molecular Formula: C18H32O3
• Mol File: 32381-42-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 9-Undecenoic acid, 11-[(2R,3S)-3-pentyloxiranyl]-, (9Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 9-Undecenoic acid, 11-[(2R,3S)-3-pentyloxiranyl]-, (9Z)-(32381-42-3)
• EPA Substance Registry System: 9-Undecenoic acid, 11-[(2R,3S)-3-pentyloxiranyl]-, (9Z)-(32381-42-3)

Safety Data

• Hazardous Substances Data: 32381-42-3(Hazardous Substances Data)

Upstream product

• 88462-46-8 (8-carboxyoctyl)triphenylphosphonium bromide 
• 105198-51-4 (Z)-(12R,13R)-12-(tert-Butyl-diphenyl-silanyloxy)-13-hydroxy-octadec-9-enoic acid methyl ester 
• 98050-12-5 tert-Butyl-((2R,3R)-5-methoxy-2-pentyl-tetrahydro-furan-3-yloxy)-diphenyl-silane 
• 98050-08-9 (2R,3R)-5-Methoxy-2-((E)-pent-1-enyl)-tetrahydro-furan-3-ol 
• 105229-01-4 (2S,3R)-3-Hydroxy-5-methoxy-tetrahydro-furan-2-carbaldehyde 
• 98050-10-3 (2R,3R)-5-Methoxy-2-pentyl-tetrahydro-furan-3-ol 
• 41059-02-3 9-bromononanoic acid 
• 2733-91-7 methyl (9Z,12S,13R)-12,13-epoxy-9-octadecenoate 
• 60-33-3 linoleic acid 
• 105229-02-5 (-)-leukotoxin B methyl ester 

Downstream Products

• 17966-13-1 (+/-)-cis-12,13-epoxy-9(Z)-octadecenoic acid 

Relevant articles and documents

Practical, enantiospecific syntheses of 14,15-EET and leukotoxin B (vernolic acid)

Cytochrome P450BM3 and its F87V mutant were exploited for a convenient, laboratory scale (1 mmol) preparation of 14(S),15(R)-epoxyeicosatrienoic acid [14(S),15(R)-EET] from arachidonic acid and (+)-leukotoxin B [(+)-12(S),13(R)-vernolic acid] from linoleic acid, respectively. Their enantiomers were accessed via a four-step chemical inversion.