324000-48-8

Basic information

• Product Name: methoxydiphenyl(prop-2-enyl)silane
• Synonyms: methoxydiphenyl(prop-2-enyl)silane
• CAS NO: 324000-48-8
• Molecular Weight: 254.404
• Mol File: 324000-48-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methoxydiphenyl(prop-2-enyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: methoxydiphenyl(prop-2-enyl)silane(324000-48-8)
• EPA Substance Registry System: methoxydiphenyl(prop-2-enyl)silane(324000-48-8)

Safety Data

• Hazardous Substances Data: 324000-48-8(Hazardous Substances Data)

Upstream product

• 6843-66-9 dimethoxy(diphenyl)silane 
• 1730-25-2 allylmagnesium bromide 

Downstream Products

• 154714-10-0 allyldiphenylethynylsilane 
• 212125-31-0 1-(allyldiphenylsilyl)prop-1-yne 
• 212125-30-9 1-(allyldiphenylsilyl)-2-phenylethyne 
• 212125-09-2 1-(allyldiphenylsilyl)hex-1-yne 
• 909805-45-4 allyl-oct-1-ynyl-diphenyl-silane 
• 1428850-52-5 C₂₅H₂₄O₂Si 
• 1380681-24-2 fluoro(diphenyl)(prop-2-enyl)silane 
• 324000-59-1 bis(3-allyldiphenylsilyl-2-propynyloxy)diphenylsilane 
• 324000-57-9 1,7-bis(allyldiphenylsilyl)-4,4-bis(methoxycarbonyl)hepta-1,6-diyne 
• 324000-58-0 1,8-bis(allyldiphenylsilylethynyl)naphthalene 
• 324000-56-8 bis(3-allyldiphenylsilyl-2-propynyl) sulfide 
• 324000-54-6 3-(allyldiphenylsilyl)prop-2-yn-1-ol 
• 324000-55-7 1-(allyldiphenylsilyl)-3-bromoprop-1-yne 

Relevant articles and documents

Meerwein's reagent mediated, significantly enhanced nucleophilic fluorination on alkoxysilanes

We developed a new facile method to fluorosilanes from alkoxysilanes using Meerwein's reagent. Our protocol afforded fluorosilanes in excellent yields in various organic solvents including acetonitrile under mild reaction conditions at room temperature. We also proposed a reaction mechanism with the probable silyloxonium intermediates. Georg Thieme Verlag Stuttgart · New York.

Ring strain-promoted allylic transposition of cyclic silyl ethers

Relief of the ring strain of medium-sized rings promotes a regioselective allylic transposition of a C-O bond when catalyzed by rhenium oxide. Through the allylic transposition, eight-membered cyclic silyl ethers undergo ring contraction to the corresponding six-membered siloxacycles.