324753-56-2

Downstream Products

• 324753-61-9 (S)-(-)-2-[(dimethyl)(vinyl)silyloxy]-2-phenylacetaldehyde N,N-diphenylhydrazone 
• 251921-02-5 N'-(2,2-dimethyl-5-phenyl-[1,2]oxasilolan-4-yl)-N,N-diphenyl-hydrazine 

Relevant academic research and scientific papers

A Silicon Tether Approach for Addition of Functionalized Radicals to Chiral α-Hydroxyhydrazones: Diastereoselective Additions of Hydroxymethyl and Vinyl Synthons

Stereocontrolled additions of hydroxymethyl and vinyl groups to chiral α-hydroxyhydrazones can be achieved by radical cyclizations using bromomethyl or vinyl radical precursors tethered via a temporary silicon connection. Tin-mediated 5-exo radical cycliz

A silicon tether approach for diastereocontrol in radical addition to chiral hydrazones

(formula presented) A radical carbon-carbon bond construction approach to chiral α-branched amines is presented. Stereocontrolled radical addition to chiral hydrazones can be achieved by virtue of conformational constraints imposed during cyclizations usi