32497-11-3Relevant academic research and scientific papers
NHCs-mediated benzoates formation directly from aromatic aldehydes and alkyl halides
Li, Yi,Du, Wenting,Deng, Wei-Ping
experimental part, p. 3611 - 3615 (2012/06/15)
A NHCs-mediated benzoates formation was developed by treatment of aromatic aldehydes with alkyl halides in the presence of oxygen. Corresponding benzoate derivatives were obtained in high yields up to 99%. The reaction mechanism was also discussed and a NHCs-mediated O-alkylation and subsequent oxidation process was proposed.
The reaction of 3-methylthiazolium derivatives with superoxide
Itoh, Takashi,Nagata, Kazuhiro,Okada, Mamiko,Ohsawa, Akio
, p. 4859 - 4870 (2007/10/02)
3-Methylbenzothiazolium salts were allowed to react with superoxide to afford dimeric bis[o-(N-formyl-N-methylamino)phenyl]disulfides and 3-methyl-2-benzothiazolones. The reaction was applied to monocyclic thiazolium salts, and novel ten-membered ring com
REACTION OF N-ALKYLTHIAZOLIUM HALIDES, INCLUDING THIAMINE, WITH SUPEROXIDE ION. CHEMISTRY AND BIOLOGICAL IMPLICATIONS.
Dondoni, Alessandro,Galliani, Guido,Mastellari, Annarosa,Medici, Alessandro
, p. 2917 - 2920 (2007/10/02)
N-alkylthiazolium halides are transformed by KO2 into the corresponding thiazolin-2-ones and thiazolin-2-thiones; the same reactions occur with thiamine, whose thiazolin-2-one pyrophosphate has been reported to be a strong inhibitor of pyruvic dehydrogenase.
