325-84-8Relevant academic research and scientific papers
Chemical oxidation of fluoroanilines to fluoroazobenzenes and fluorophenazines with potassium ferricyanide and potassium hydroxide
Leyva, Elisa,Medina, Concepcion,Moctezuma, Edgar,Leyva, Socorro
, p. 1712 - 1715 (2007/10/03)
The oxidation of several fluoroanilines with potassium ferricyanide and potassium hydroxide is described. In this oxidation, the major products are fluoroazobenzenes. In the case of 2-fluoro-substituted anilines, heterocyclic fluorophenazines were obtained in low to moderate yields. The optimal conditions for the reaction and the mechanism are presented.
Photochemistry of Fluorinated Aryl Azides in Toluene Solution and in Frozen Polycrystals
Leyva, Elisa,Munoz, Daniel,Platz, Matthew S.
, p. 5938 - 5945 (2007/10/02)
Several fluorinated triplet aryl nitrenes have been generated in low-temperature polycrystals by photolysis of the corresponding azides.Upon extended photolysis at -196 deg C the nitrenes abstract hydrogen from frozen toluene to give anilino-benzyl radical pairs, which subsequently combine to give CH insertion products.The radical pairs and the triplet nitrenes have been detected by EPR.In toluene solution, the major reaction products are tar, the corresponding fluorinated anilines, and azo compounds.
