325125-17-5

Basic information

• Product Name: cis-bis(difluoroboryl)(1,4-bis(diphenylphosphino)butane)platinum(II)
• CAS NO: 325125-17-5
• Molecular Weight: 719.173
• Mol File: 325125-17-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-bis(difluoroboryl)(1,4-bis(diphenylphosphino)butane)platinum(II)(CAS DataBase Reference)
• NIST Chemistry Reference: cis-bis(difluoroboryl)(1,4-bis(diphenylphosphino)butane)platinum(II)(325125-17-5)
• EPA Substance Registry System: cis-bis(difluoroboryl)(1,4-bis(diphenylphosphino)butane)platinum(II)(325125-17-5)

Safety Data

• Hazardous Substances Data: 325125-17-5(Hazardous Substances Data)

Upstream product

• 114441-16-6 Pt(C₂H₄)(1,3-bis(diphenylphosphino)butane) 
• 13965-73-6 diboron tetrafluoride 

Relevant articles and documents

Transition metal complexes incorporating the BF2 ligand formed by oxidative addition of the B-B bond in B2F4

The reactions between B2F4 and the platinum and iridium complexes [Pt(PPh3)2(η-C2H4)], [Pt(dppb)(r)-C2H4)] [dppb = l,4-bis(diphenylphosphino)butane] and trans-[IrCl(CO)(PPh3)2] afforded the difluoroboryl complexes cis-[Pt(BF2)2(PPh3)2], cis-[Pt(BF2)2(dppb)] and fac-[Ir(BF2)3(CO)(PPh3)2] respectively all of which have been characterised by X-ray crystallography. The isoelectronic platinum dppb nitrito complex cw-[Pt(NO2)2(dppb)] has also been prepared and structurally characterised. The Royal Society of Chemistry 2000.